By means of the anchoring effect and the intrinsic basicity of nitrogendoped carbon nanotubes ncnts, iron nanoparticles were conveniently immobilized on ncnts without surface premodification. It is caused by that lengths of bonds nc and cc differ a little 1. Concentration profiles derived from electron energyloss line spectra show that boron and nitrogen are correlated in a onetoone ratio. Nitrogen doping effects on carbon nanotubes and the origin. However, although this is true in the case of boron doping, the ionization potential was not a correct indicator. Phosphorusdoping activates carbon nanotubes for efficient. Structural study of nitrogendoping effects in bambooshaped multiwall carbon nanotubes article pdf available in applied physics letters 8415. Pdf nitrogen doping in carbon nanotubes researchgate. Electronic properties of nitrogendoped carbon nanotubes with.
The nitrogen species would serve as doping heteroatoms in the formation of carbon materials, which would help to improve the conductivity and energy. Therefore,itshouldbepossibletoavoidthose detrimental functionalization processes using strong acid and to attach pt nanoparticles onto the surface of cnx e. The effect of nitrogendoped multiwall carbon nanotubes cn x on the proliferation of nih3t3 murine fibroblasts is presented. Nitrogen is one of promising dopants for carbonbased materials since it is a neighbouring element to carbon in periodic table. Nano express open access effect of sulfur on enhancing.
Theoretical investigation on singlewall carbon nanotubes. Carbon nanotubes thermal and chemical durability nitrogen doping introduction nitrogendoped carbon nanotubes cn x tubes have attracted particular research interest because of their applications in producing different types of nanodevices with tuning properties such as nanoscale electronics huang et al. The graphitic nitrogen plays a determining role in enhancing their activity by speeding up the activation of oxygen and decreasing the overall activation energy of t. Nickel supported on nitrogendoped carbon nanotubes as. The asobtained sno 2 cnx composites were characterized using xray powder diffraction, scanning electron microscopy, and transmission electron microscopy. Controlled doping of isolated swnts with nitrogen was achieved. Carbon c nanotubes nt nowadays represent one of the most active research fields.
Jan 15, 2020 the electrochemical nitrogen reduction reaction nrr as an energyefficient approach for ammonia synthesis is hampered by the low ammonia yield and ambiguous reaction mechanism. Promotion effects of nitrogen doping into carbon nanotubes. Carbon nanotubes electrontransfer nitrogen doping vertically aligned carbon nanotubes produced with in situ doping of nitrogen cn x nts during chemical vapor deposition exhibit unique structural and electrochemical properties, which are strongly correlated with their nitrogen n doping level. Carbon nanotubes thermal and chemical durability nitrogen doping introduction nitrogen doped carbon nanotubes cn x tubes have attracted particular research interest because of their applications in producing different types of nanodevices with tuning properties such as nanoscale electronics huang et al. The effective doping of nitrogen into cnts is mainly achieved in situ during cnt growth 1216,19, and ndoping content is usually controlled by adjusting the ratio of carbon source to nitrogen source 16,19, which is disadvantageous for increasing the doping content of. Various applications of carbon nanotubes require their chemical modification inorder to tunecontrol their physicochemical properties.
Figure 2 from nitrogendoped carbon nanotube and graphene. Photoassisted electronic transport in impuritydoped carbon. The use of carbon nanotubes with and without nitrogen doping as support for ruthenium catalysts in the ammonia decomposition reaction. N 2 physisorption, xps, xrd, tem, and co chemisorption were employed to investigate the effects of nitrogen doping on the structure of cnts and the state of ru particles supported on cnts. Effect of nitrogen doping on raman spectra of multi. The bulk structure and the surface texture of cnts remain unchanged by such nitrogen doping. This dissertation discusses the influence of nitrogen doping ndoping on the electronic and catalytic properties of carbon nanotubes cnts. New doping method improves properties of carbon nanotubes. Pichler a a faculty of physics, university of vienna, strudlhofgasse 4, a1090 vienna, austria. Synthesis of nitrogen doped carbon nitrogen n is a neighboring element of carbon in the periodic table, and its electronegativity 3.
Nitrogen doped carbon nanotubes ncnts can be produced through five main methods. Pdf nitrogendoped carbon materials, including nitrogendoped carbon nanotubes ncnts and nitrogendoped graphene ng, have attracted increasing. Nitrogendoped carbon materials, including nitrogendoped carbon nanotubes. The literature regarding the study of properties and applications of pristine cnt has progressed enormously in the recent years and a great interest has been lately observed towards improving and controlling their properties through different functionalization methods. The electrochemical nitrogen reduction reaction nrr as an energyefficient approach for ammonia synthesis is hampered by the low ammonia yield and ambiguous reaction mechanism. Pdf nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on. Jan 12, 2011 the effective doping of nitrogen into cnts is mainly achieved in situ during cnt growth 1216, 19, and ndoping content is usually controlled by adjusting the ratio of carbon source to nitrogen source 16, 19, which is disadvantageous for increasing the doping content of cnts produced with liquid carbon source. The various issues related to the synthesis of nitrogen and boron. The effective doping of nitrogen into cnts is mainly achieved in situ during cnt growth 1216, 19, and ndoping content is usually controlled by adjusting the ratio of carbon source to nitrogen source 16, 19, which is disadvantageous for increasing. Mananghaya, carbon nanotubes doped with nitrogen, pyridinelike nitrogen defects and transition metal atoms, journal of korean chemical society, vol.
Nitrogen doping effects on microstructure of multiwalled. Effects of nitrogendoping on the microstructure, bonding and. Dec 08, 2017 in this video, i have discussed about doping of cnt by n, structural change and its application. Nitrogen doped carbon nanotubes ncnts were synthesized by pyrolysis of 4pyridine4ylmethylideneaminophenylferrocene in a solution of either acetonitrile or toluene as carbon source. Isolated single wall carbon nanotubes swnts were prepared on bare quartz and sio2si substrates using a chemical vapor deposition process in which xylene was used as the carbon source. As such, doping carbon nanotubes with nitrogen heteroatoms as in the ncnt electrodes can efficiently create the metalfree active sites for electrochemical reduction of o 2. Effect of sulfur on enhancing nitrogendoping and magnetic. Nitrogendoped carbon materials, including nitrogendoped carbon nanotubes ncnts and nitrogendoped graphene ng, have attracted increasing attention for oxygen reduction reaction orr in metalair batteries and fuel cell applications, due to their optimal properties including excellent electronic conductivity, 4e. Thermal and chemical durability of nitrogendoped carbon. The inner diameter and wall thickness of the pncnts are about 55 nm and 22 nm, respectively. This dissertation discusses the influence of nitrogen doping n doping on the electronic and catalytic properties of carbon nanotubes cnts. The synthesis of nitrogendoped multiwalled carbon nanotubes. The practical background lies in the fact that defined n. C was found to be the most favourable condition for ncnt growth.
Effect of nitrogen doping on the mechanical properties of. In this case, dopingrefers tothe substitution of a carbon atom with oth er elements such as boron or nitrogen, andis expectedto have significant impact on th e charge transport properties of the nanotubes. Carbon nanotubes cnts and nitrogendoped carbon nanotubes cnx were synthesized by the floating catalyst chemical vapor deposition fccvd method. Composite sheets and nanotubes of different morphologies containing carbon, boron, and nitrogen were grown in the electric arc discharge between graphite cathodes and amorphous boronfilled graphite anodes in a nitrogen atmosphere. Jan 15, 2020 among the various potential dopants, nitrogen is presently considered as an excellent doping component for carbon based materials.
Synthesis of nitrogendoped carbon nitrogen n is a neighboring element of carbon in the periodic table, and its electronegativity 3. Impact on electronic properties and growth selectivity hamid reza barzegar, eduardo graciaespino, tiva sharifi, florian nitze, and thomas wagberg. Effect of nitrogen doping on the electronic and catalytic. Nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on quasi1d electrical conductors, and for applications such. Femn nanoparticles encapsulated in nitrogendoped carbon nanotubes as a peroxymonosulfate activator for acetamiprid degradation pijun duan, a tengfei ma, a yue yue, b yanwei li, b xue zhang, a yanan shang, a baoyu gao, a qingzhu zhang, b qinyan yue a and xing xu a. Nitrogen doping mechanism in small diameter singlewalled. First principles calculation of field emission from carbon.
The reason why nitrogendoped carbon nanotubes are the target of several investigations is explained not only from the stateoftheart research point of view but special attention is given to present the results available in the literature weighed against the ideal materials expected for applications. Nitrogen doping of single and multiwalled carbon nanotubes is of great interest both fundamentally, to explore the effect of dopants on quasi1d electrical conductors, and for applications such as field emission tips, lithium storage, composites and nanoelectronic devices. Herein, phosphorusdoped carbon nanotube pcnts is developed as an efficient metalfree electrocatalyst for nrr with a remarkable nh3 yield of 24. Nitrogendoped carbon nanotube and graphene materials. Femn nanoparticles encapsulated in nitrogendoped carbon.
Nitrogen and boron doping in carbon nanotubes chris ewels. Proposed growth models for ncnt synthesis are also reported. Effect of sulfur on enhancing nitrogendoping and magnetic properties of carbon nanotubes tongxiang cui1, ruitao lv1, zhenghong huang1, feiyu kang1, kunlin wang2, dehai wu2 abstract sulfur s is introduced as an additive in the growth atmosphere of carbon nanotubes cnts in. Jan 14, 2016 although nitrogen doped carbon nanotubes are a very poor hydrogen oxidation catalyst, as a support, it increases the catalytic performance of nickel nanoparticles by a factor of 33 mass activity. The incorporation of n atom into a graphene lattice plane could modulate the local electronic properties, as it could form strong bonds with carbon atoms because of its. We report on the usage of a simple microfabricated device that works in conjunction with a quantitative nanoindenter within a scanning electron microscope sem chamber, for the in situ quantitative tensile testing of individual catalytically grown pristine and nitrogendoped multiwall carbon nanotubes mwnts. Doping of carbon nanotubes sergey bulyarskiy springer. The doping of carbon nanotubes with nitrogen and their potential applications p. The samples were prepared from toluene and acetonitrile taken in different proportion. Introduction since the discovery of polyhedral carbon clusters fullerenes in 1985,1 new graphitelike nanostructures such as carbon nanotubes cnts2 and related nanostructures spheres,3 onions,4 fibres,5 horns6, etc. Nitrogendoped carbon nanotubes cnx contain nitrogenated sites that are chemicallyactive. We first provide an introduction to the field of nitrogen doped carbon nanotubes ncnts and. Walled carbon nanotubes doped with nitrogen and boron.
In addition, nitrogendoped carbon itself has a certain activity. Effects of nitrogen doping on the structure of carbon. Pdf growth, nitrogen doping and characterization of. The two types of mwnts were found to possess similar strengths but different. Nitrogendoped carbon nanotubes ncnts can be produced through five main methods. Substitutional doping with heteroatoms is known to be an effective way to tune the electronic properties of the cnts. There is a huge interest in the use of carbon nanotubes in biology, and substitutional doped tubes may prove to be the material of choice for these applications. The two types of mwnts were found to possess similar strengths but different load. Three different catalysts co, fe, and ni were used to synthesize nitrogendoped cnts ncnts by chemical vapor deposition technique. Nitrogen doping effects on carbon nanotubes and the origin of.
One way for achieving thiscontrol is by carrying out doping. The book presents examples of specific calculations for doping of carbon nanotubes with oxygen, hydrogen, nitrogen and boron, together with numerous experimental results and a comparison with the authors thermodynamic calculations. Carbon nanotubes, cvd synthesis, nitrogen doping, acetonitrile, fecocaco 3 catalyst. Nitrogendoped carbon nanotubepolymer nanocomposites towards. Although nitrogendoped carbon nanotubes are a very poor hydrogen oxidation catalyst, as a support, it increases the catalytic performance of nickel nanoparticles by a factor of 33 mass activity.
The photocatalytic activity of asprepared sno 2 cnx for degradation rhodamine b under. Nitrogendoped carbon nanotubes ncnts were synthesized by pyrolysis of 4pyridine4ylmethylideneaminophenylferrocene in a solution of either acetonitrile or toluene as carbon source. The doping of carbon nanotubes with nitrogen and their. The graphitic nitrogen plays a determining role in enhancing their activity by speeding up the activation of oxygen and. Nitrogen doping has been successfully utilized to alter the. We demonstrate that nitrogen doping occurs as single atoms in different bonding. The soconstructed fencnts catalyst presents superb catalytic performance in fts with high selectivity for lower olefins of up to 46. Bulk nitrogen doping can efficiently improve the catalytic performance of carbon nanotubes cnt in oxidative dehydrogenation of propane odh. Pdf nitrogendoped carbon nanotube and graphene materials. Nitrogen doping on carbon nanotubes cnts was carried out using n 2 microwave plasma at the powers of 200 and 400 w. Nov 11, 2010 we report on the usage of a simple microfabricated device that works in conjunction with a quantitative nanoindenter within a scanning electron microscope sem chamber, for the in situ quantitative tensile testing of individual catalytically grown pristine and nitrogen doped multiwall carbon nanotubes mwnts. In the xray photoelectron spectroscopy observations. Doping 10, 0semiconductor nanotubes with nitrogen and. Enhancement of thermomechanical stability for nanocomposites.
The presence of nitrogen atoms in the graphitic sheets was assumed to have led to the formation of kinks whose motion induced by straining could have resulted in the plastic deformation of the carbon nanotubes. Pdf the use of carbon nanotubes with and without nitrogen. Revealing the enhanced catalytic activity of nitrogendoped. These properties have been studied using a variety of techniques, in order to both qualitatively and quantitatively analyze the relationship between the nitrogen concentration and observed properties. This study investigates the impact of nitrogen doping on the performance of carbon nanotube cntpolymer nanocomposites for thermoelectric applications. Unusually high dispersion of nitrogen doped carbon nanotubes in dna solution.
Sno 2 nanoparticles coated on nitrogendoped carbon nanotubes were prepared successfully via a simple wetchemical route. Among the various potential dopants, nitrogen is presently considered as an excellent doping component for carbonbased materials. Doping of a carbon 10,0 nanotube by atom of nitrogen the atom of nitrogen also is well inscribed in geometry of a nanotube, not calling essential strain of its nanostructure figure 8. Nitrogendoped carbon nanotubes synthesised by pyrolysis of. Effects of nitrogendoped multiwall carbon nanotubes on murine.
Nitrogen doping of metallic singlewalled carbon nanotubes. Nitrogen doped carbon nanotubes from organometallic. Pyridinetype in which each n atom is bonded to two carbon atoms. Researchers from the university of calgary in canada and washington state university tricities in the us manipulated the structure of cnts by introducing nitrogen between carbon atoms in cnts, and succeeded in improving the charge storage capacity of cntpolymer nanocomposites. Jan 12, 2011 the effective doping of nitrogen into cnts is mainly achieved in situ during cnt growth 1216,19, and n doping content is usually controlled by adjusting the ratio of carbon source to nitrogen source 16,19, which is disadvantageous for increasing the doping content of cnts produced with liquid carbon source. The doping of carbon nanotubes with nitrogen and their potential applications, carbon, 482010 575586. Oxygen and nitrogen doping in single wall carbon nanotubes.
Pt nanoparticles were deposited onto the two catalyst supports with the ethylene glycol reduction method. Nitrogen doping mechanism in small diameter singlewalled carbon nanotubes. This is mainly inspired in the possible applications such structures can have. Nitrogendoped carbon nanotube and graphene materials for. Doping graphitic and carbon nanotube structures with boron. Carbon nanotubes electrontransfer nitrogendoping vertically aligned carbon nanotubes produced with insitu doping of nitrogen cn x nts during chemical vapor deposition exhibit unique structural and electrochemical properties, which are strongly correlated with their nitrogen n doping level. Nitrogendoped carbon nanotubepolymer nanocomposites. Preparation and photocatalytic properties of sno2 coated on. The electronic properties of 10, 0semiconducting singlewalled carbon nanotubes swcnts containing structural defects such as vacancies single and divacancies, and pyridinic nitrogen atoms, are investigated using firstprinciples density functional theory. Owens, based on theoretical computations, expected that both boron and nitrogen doping will not enhance eld emission based on the fact that they increase the ionization energy of carbon nanotubes. Electronic properties of nitrogen doped carbon nanotubes with. Yale university researchers have developed a simple method for controlling the doping of carbon nanotubes cnts, a chemical process that.
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